阻隔PET的合成及性能研究

聚对苯二甲酸乙二醇酯(PET)因其环保性能和低成本在食品包装领域应用越来越大,随着食品包装市场的不断升级,对包装材料也提出了更高的需求.近年,特别是在高阻隔包装材料领域需求量日益增多.PET本身具备一定阻隔性能属于中等阻隔材料,但在高阻隔领域其性能显得不足.为进一步提高PET的阻隔性能,同时保持其力学性能不受影响,选用反式富马酸为改性单体,通过利用其基团柔性、憎水性和不饱和键配合催化母粒后氧化消耗氧气,获得了高阻隔改性共聚酯,提升了PET阻隔能力和保证了其冲击强度等性能.力学性能测试表明:添加少量的富马酸可以提升PET冲击强度,但富马酸含量增加后冲击强度有所下降,拉伸强度随着富马酸含量增加反而降低.共聚酯的水蒸汽透过量和氧气透过率均较PET有较大提升,改性后能够适用于有高阻隔要求的食品包装领域.     

Simultaneous bioelectricity generation and pollutants removal of sediment microbial fuel cell combined with submerged macrophyte

A submerged macrophyte sediment microbial fuel cell (SP-SMFC) was constructed in this study. Ceratophyllum demersum L., Vallisneria natans, Hydrilla verticillate were chosen as the submerged plants to form cer-SMFC, val-SMFC, hyd-SMFC systems. Plant groups showed the advantage of bioelectricity generation and pollutants removal compared with the unplanted system. The cer-SMFC group stood out with the maximum power density as 24.56 mW m^?2 and the average pollutants removal in overlying water (COD: 81.16%, TN: 65.27%, TP: 79.10%) and in sediments (TN: 26.40%, TP: 21.79%). The determination of root exudates and radial oxygen loss (ROL) demonstrated that C. demersum L. was superior to other studied submerged macrophytes. More root exudates may contribute to an increase in available substrates for electrochemically active bacteria and other microorganisms. Higher enzyme activities were obtained in three SP-SMFCs (especially in cer-SMFC). ATPase and APA activities in cer-SMFC group were increased by over 40% compared with the control. The results indicated that the presence of plants enhanced the microorganism activities, thereby improving bioelectricity generation and pollutants removal. This study will facilitate the application of SP-SMFC technology as an alternative for in situ remediation of polluted sediments.     

High strain rate compressive response of the Cf/SiC composite

Carbon fiber reinforced ceramic owns the properties of lightweight, high fracture toughness, excellent shock resistance, and thus overcomes ceramic's brittleness. The researches on the advanced structure of astronautics, marine have exclusively evaluated the quasi-static mechanical response of carbon fiber reinforced ceramics, while few investigations are available in the open literature regarding elastodynamics. This paper reports the dynamic compressive responses of a carbon fiber reinforced silicon carbide (C_f/SiC) composite (CFCMC) tested by the material test system 801 machine (MTS) and the split Hopkinson pressure bar (SHPB). These tests were to determine the rate dependent compression response and high strain rate failure mechanism of the C_f/SiC composite in in-plane and out-plane directions. The in-plane compressive strain rates are from 0.001 to 2200?s^?1, and that of the out-plane direction are from 0.001 to 2400?s^?1. The compressive stress-strain curves show the C_f/SiC composite has a property of strain rate sensitivity in both directions while under high strain rate loadings. Its compressive stiffness, compressive stress, and corresponding strain are also strain rate sensitive. The compressive damage morphologies after high strain rate impacting show different failure modes for each loading direction. This study provides knowledge about elastodynamics of fiber-reinforced ceramics and extends their design criterion with a reliable evaluation while applying in the scenario of loading high strain rate.     

Preparation of manganese monoxide@reduced graphene oxide nanocomposites with superior electrochemical performances for lithium-ion batteries

Manganese monoxide (MnO) nanowire@reduced graphene oxide (rGO) nanocomposites are synthesized using a simple hydrothermal method combined with a calcination process. The structural and morphological characterization of the composites indicates that the MnO nanowires homogeneously anchor on both sides of the cross-linked rGO. The nanocomposites exhibit a high surface area of 126.5?m² g^?1. When employed as an anode material for lithium-ion batteries, the nanocomposites exhibit a reversible capacity of 1195 mAh g^?1 at a current density of 0.1?A?g^?1, with a high charge-discharge efficiency of 99.2% after 150 cycles. The three-dimensional architecture of the present materials exhibits high porosity and electron conductivity, significantly shortening the diffusion path of lithium ions and accelerating their reaction with the electrolyte, which greatly improves the lithium-ion storage properties. These excellent electrochemical performances make the composite a promising electrode material for lithium-ion batteries.     

浓香型白酒窖泥放线菌的原位分离及代谢特性研究

以川南某浓香型白酒生产企业50年窖龄且发酵正常的窖泥为研究对象。通过高通量测序技术分析细菌群落结构以及放线菌群落结构,利用原位分离法从中分离得到2株放线菌,结合形态鉴定、生理生化和16S rRNA基因序列比对分析确定菌种属,并对其进行耐酸、耐乙醇特性研究,基于风味导向思路,分别对2株菌进行液态培养和固态培养,采用顶空固相微萃取法和气相色谱质谱联用对发酵挥发性产物进行分析,为放线菌的相关研究和应用提供理论参考。结果显示,放线菌在该窖泥样品含有较高操作分类单元(operational taxonomic unit,OTU),相对丰度达(10.7±3.4)%,且主要分布于链霉菌亚目(Streptomycineae)和科里氏杆菌亚目(Coriobacterineae)。采用原位分离法分离放线菌,将分离得到的2株菌编号为A1、A2,菌株A1鉴定为桑氏链霉菌(Streptomyces sampsonii),菌株A2鉴定为鲁地链霉菌(Streptomyces rutgersensis)。菌株A1、A2均可在pH>4.3或乙醇体积分数<6%的环境中生长。菌株A1在液态和固态发酵条件下都会产生大量土臭素以及萜烯类物质,菌株A2在液态条件下能产生多种酯类,其中己酸乙酯相对含量(5.384%)较高,而固态条件下能够检测出大量的3-羟基-2丁酮、2,3-丁二醇和吡嗪类物质。     

无损检测技术在水利工程质量检测中的应用

当前,水利项目不仅可满足人们的需求,而且越来越关注多样化发展.为提高项目质量,有必要充分研究无损检测技术的功能和作用.对液压结构的全面测试可最大限度地减少对液压结构的不利影响,并扩大液压结构的使用范围,在此基础上,对无损检测技术在水利工程质量检测中的应用进行了研究.     

In-situ measurement of reflection coefficient and its application to predicting combustion instability in a gas turbine combustor

Journal of Mechanical Science and Technology - Here, a procedure that uses in-situ data recorded by two microphones placed inside an operating gas turbine combustor to determine the reflection...     

Validation of avenanthramide and other phenolic compounds in oats and sprouted oats and their antimicrobial properties against Escherichia coli O157:H7

Food Science and Biotechnology - Oat contains a variety of phenolic compounds, including avenanthramides, which are found only in oats. This study was conducted to establish the quantitative...     

Heterogeneous Bimetallic Mo-NiPx/NiSy as a Highly Efficient Electrocatalyst for Robust Overall Water Splitting

Highly efficient electrocatalysts composed of earth-abundant elements are desired for water-splitting to produce clean and renewable chemical fuel. Herein, a heteroatomic-doped multi-phase Mo-doped nickel phosphide/nickel sulfide (Mo-NiP_x/NiS_y) nanowire electrocatalyst is designed by a successive phosphorization and sulfuration method for boosting overall water splitting (both oxygen and hydrogen evolution reactions (HER)) in alkaline solution. As expected, the Mo-NiP_x/NiS_y electrode possesses low overpotentials both at low and high current densities in HER, while the Mo-NiP_x/NiS_y heterostructure exhibits high active performance with ultra-low overpotentials of 137, 182, and 250 mV at the current density of 10, 100, and 400 mA cm⁻² in 1 m KOH solution, respectively, in oxygen evolution reaction. In particular, the as-prepared Mo-NiP_x/NiS_y electrodes exhibit remarkable full water splitting performance at both low and high current densities of 10, 100, and 400 mA cm⁻² with 1.42, 1.70, and 2.36 V, respectively, which is comparable to commercial electrolysis.